How should we add calcium chloride to a swimming pool? How can we make sure we're handling it safely, and properly, to avoid unintended consequences? Adding calcium is not as simple as it sounds...you don't just throw it in the pool. Calcium chloride doesn't dissolve the same way as dry acid, sodium bicarb or a non-chlorine shock; calcium chloride gives off a lot of heat. Like any other dry chemical, however, calcium chloride should be pre-dissolved in a bucket prior to adding to the pool. Let's explain.