Have you ever asked "what's the difference between pH and alkalinity? Many of us in aquatics confuse total alkalinity and pH. It’s understandable, given how blurred the line is between words like “alkaline” and “alkalinity.” Indeed, alkalinity and pH in water chemistry are related, but not the same. This article will explain the distinction between them.
What is pH?
pH stands for “power of Hydrogen;” the measure of the concentration of hydrogen ions in a solution. We measure how acidic or basic (also called alkaline) substances are by using the pH scale. The pH scale goes from 1 to 14, and is relative to pure water, which has a perfectly neutral pH of 7. The scale is logarithmic, which means each whole number on the 1-14 pH scale is 10 times more or less than the numbers around it. For example, something with a pH of 6 is 10 times more acidic than pure water. Something with a pH of 5 is 10 times more acidic than 6, which means it’s 100 times more acidic than pure water (10x10=100).
To put the pH scale in perspective, let’s do some quick math. Trichlor, a popular type of stabilized chlorine used primarily in outdoor pools, has a pH of about 3. For this math, let’s just round it to exactly 3.0. How acidic is 3.0pH Trichlor compared to 7.0pH pure water? Let’s figure it out.
(7.0pH - 3.0pH) = 4.0
Logarithmic scale means 104, or 10x10x10x10 = 10,000
Trichlor is 10,000 times more acidic than pure water.
Don’t worry about the math, it’s just to explain the pH scale itself. From a water chemistry perspective, the ideal pH for a swimming pool or spa is between 7.4-7.6. If your pH is higher (more alkaline), you can lower it by injecting carbon dioxide (CO2) or adding some muriatic acid. If your pH is lower (more acidic), you can raise it by adding something alkaline, like soda ash or sodium bicarbonate (baking soda).
The role of pH in water chemistry
Managing pH is a critical component of maintaining healthy water chemistry. It is so important because pH is a driving factor in the Langelier Saturation Index (LSI), and also because pH determines how effective chlorine will be. The lower the pH, the stronger chlorine will be. That being said, it is also important to understand that the type of chlorine you use affects both pH and total alkalinity. That’s because different types of chlorine have very different pH levels. For example, Trichlor (mentioned above) has a low pH. But Calcium Hypochlorite (Cal Hypo) has a high pH of almost 12. As an aside, never mix different types of chlorine. They can explode. Literally.
Low pH can cause damage to pool liners and etching of plaster; corrosion of metal components in and around the pool; skin and eye damage, as well as general patron discomfort; and a reduction of total alkalinity. On the other hand, high pH water can cause scale formation; metal stains; cloudy water; poor efficiency of chlorine, and also can cause skin and eye irritation. Just stay within the 7.4-7.6 range to avoid those problems.
What is Total Alkalinity?
Unlike pH—which is basically a scale to measure against—total alkalinity is a measurement of all alkaline substances dissolved in the water. These substances are primarily carbonates, bicarbonates and hydroxides, along with a few others. These alkaline substances buffer pH in the water by neutralizing acids. In other words, total alkalinity is a measurement of the water’s ability to resist change in pH.
Total alkalinity is measured in parts-per-million (ppm), and the ideal range is from 80-120ppm, depending on the type of chlorine you use. For example, Trichlor has a low pH of about 3, which means you will want your total alkalinity closer to 120ppm, given how acidic it is. Liquid bleach, however, has a high pH of 13, so you can have lower alkalinity, like 80-100ppm. Note: one of the byproducts of using liquid bleach (sodium hypochlorite) is sodium hydroxide, which contributes to total alkalinity and raises pH.
Did you notice that total alkalinity is not measured on the pH scale?
This is an important distinction to make, because this is usually how pH and alkalinity get confused. Total alkalinity is measured by the amount (ppm) you have in the water, not by how alkaline (pH) the water is. 'Alkalinity increaser' products are prevalent in the pool industry, though they do have an effect on pH. If you are in the market for an alkalinity increaser, the most common is sodium bicarbonate. As for 'alkalinity decreaser' products, they will be an acid like muriatic acid.
The role of total alkalinity in water chemistry
If you’re a pool operator, you probably already know that pH can fluctuate up and down. And when it does, the pool is constantly fighting against you. Having the right level of total alkalinity is a good thing, because it helps to keep the pH stabilized. Another way to think of total alkalinity's role is that it neutralizes acid.
You could have a ton of 8.3pH Sodium Bicarb floating around in the water, and have the same pH as if you added a smaller amount of 13.0pH soda ash. But the total alkalinity would be higher for the Sodium Bicarb, because there’s simply more of it in the water.
How to increase total alkalinity
If you want to increase total alkalinity in a swimming pool, you need to know the gallonage of the pool, and your pH. It helps to have an accurate dosing calculator. Raising alkalinity is as simple as adding carbonates, bicarbonates or hydroxides to the water. Two of the most common pool products are sodium carbonate (soda ash) and sodium bicarbonate (sodium bicarb).
How to lower total alkalinity
You can lower alkalinity using acid. Some experts recommend a "acid column pour" to lower alkalinity, but we do not. In our experience--and indeed, scientific experiments back this up--column pouring is no more beneficial than dilution. We recommend diluting the acid in a bucket of water, and evenly pouring it around the pool. Besides, column pouring can severely lower the pH in a concentrated location (at the bottom of your pool!), which can throw the LSI off, and in turn, etch the surface.
Lowering pH without affecting total alkalinity can be accomplished using carbon dioxide. But that's a topic for another time.
Maintain total alkalinity within the range of 80-120ppm for healthy pool chemistry. Use an alkalinity increaser like sodium bicarbonate to raise total alkalinity, or an acid to lower it. When using high-pH chlorines like liquid bleach or Cal Hypo, stay lower in the range, like 80-100ppm. For low pH chlorines like Trichlor, 110-120ppm is where you want to be. Consult your test kit or the dosing calculator on the Orenda App for specific numbers.
One final note: another pH buffer is calcium, which serves a similar function to total alkalinity. Remember, calcium carbonate (scale) and calcium hydroxide (plaster dust or crystals) both count toward total alkalinity.